The Stoltz Group - Publications

"Palladium-Catalyzed Enantioselective Decarboxylative Allylic Alkylation of Acyclic α-N-Pyrrolyl/Indolyl Ketones" Remi Lavernhe, Eric J. Alexy, Haiming Zhang, and Brian M. Stoltz. Org. Lett. 2020, Article ASAP.. [Supporting Information].
"The Total Synthesis of (–)-Scabrolide A" Nicholas J. Hafeman, Steven A. Loskot, Christopher E. Reimann, Beau P. Pritchett, Scott C. Virgil, and Brian M. Stoltz. J. Am. Chem. Soc. 2020, Just Accepted Manuscript. [Supporting Information]. ChemRxiv Preprint.
"Enantioselective Total Synthesis of (–)-Myrifabral A and B" Tyler J. Fulton, Anthony Chen, Michael Bartberger, and Brian Stoltz. ChemRxiv. Preprint. DOI: http://10.26434/chemrxiv.11900331.v1 [Supporting Information].
"Iridium-Catalyzed Enantioselective and Diastereoselective Hydrogenation of 1,3-Disubstituted Isoquinolines" Alexia N. Kim, Aurapat Ngamnithiporn, Eric R. Welin, Martin T. Daiger, Christian U. Grünanger, Michael D. Bartberger, Scott C. Virgil, and Brian M. Stoltz. ACS Catal. 2020, 10, 3241–3248. [Supporting Information].
"Enantioselective Synthesis of 15-Deoxy‐Δ^12,14-Prostaglandin J₂" Jiaming Li, Brian M. Stoltz, and Robert H. Grubbs. Org. Lett. 2019, Article ASAP. [Supporting Information].
"Palladium‐Catalyzed Enantioselective Decarboxylative Allylic Alkylation of Protected Benzoin‐Derived Enol Carbonates" Rémi Lavernhe, Eric J. Alexy, Haiming Zhang, Brian M. Stoltz. Adv. Synth. Catal. 2019, Early View. [Supporting Information].
"Progress toward the Enantioselective Synthesis of Curcusones A–D via a Divinylcyclopropane Rearrangement Strategy" Austin C. Wright, Chung Whan Lee, and Brian M. Stoltz. Org. Lett. 2019, Article ASAP. [Supporting Information].
"Cu‐Catalyzed Enantioselective Allylic Alkylation with a γ‐ Butyrolactone‐Derived Silyl Ketene Acetal" Carina Jette, Zhengjia Tong, Ryan Hadt, and Brian Stoltz. Angew. Chem. Int. Ed. 2019, Accepted Article. [Supporting Information].
"Enantioselective Alkynylation of Trifluoromethyl Ketones Catalyzed by Cation‐Binding Salen Nickel Complexes" Dongseong Park, Carina I. Jette, Jiyun Kim, Woo-ok Jung, Yongmin Lee, Jongwoo Park, Seungyoon Kang, Min Su Han, Brian Stoltz, and Sukwon Hong. Angew. Chem. Int. Ed. 2019, Accepted Article. [Supporting Information].
"Synthesis of non-natural cyanthiwigin–gagunin hybrids through late-stage diversification of the cyanthiwigin natural product core" Kelly E. Kim, Yuka Sakazaki, and Brian M. Stoltz. Tetrahedron 2019, In Press.
"Palladium-Catalyzed Decarboxylative Asymmetric Allylic Alkylation of 1,4-Diazepan-5-ones" Zachary P. Sercel,^† Alexander W. Sun,^† and Brian M. Stoltz. Org. Lett. 2019, Article ASAP. ^†Equal Contribution. [Supporting Information].
"Stereospecific Overman Rearrangement of Substituted Cyclic Vinyl Bromides: Access to Fully Substituted α-Amino Ketones" Álvaro Velasco-Rubio, Eric J. Alexy, Makoto Yoritate, Austin C. Wright, and Brian M. Stoltz. Org. Lett. 2019, Article ASAP. [Supporting Information].
"Modularity: Adding New Dimensions to Total Synthesis" Alexander W. Sun,† Sebastian Lackner,† and Brian M. Stoltz. Trends in Chemistry 2019, 1, 630–643.
"Enantioselective Construction of the Tricyclic Core of Curcusones A–D via a Cross-electrophile Coupling Approach" Austin C. Wright and Brian M. Stoltz. Chem. Sci. 2019, Advance Article/em>. [Supporting Information].
"A Small-scale Procedure for Acid-catalyzed Ketal Formation" Austin C. Wright, Yun Emily Du, and Brian M. Stoltz. J. Org. Chem. 2019, 84, 11258–11260.
"Incorporation of a chiral gem-disubstituted nitrogen heterocycle yields an oxazolidinone antibiotic with reduced mitochondrial toxicity" Alexander W. Sun, Philip L. Bulterys, Michael D. Bartberger, Peter A. Jorth, Brendan M. O'Boyle, Scott C. Virgil, Jeff F. Miller, Brian M. Stoltz. Bioorg. Med. Chem. Lett. 2019, 29, 2686–2689.
"Unified Enantioselective, Convergent Synthetic Approach toward the Furanobutenolide-Derived Polycyclic Norcembranoid Diterpenes: Synthesis of a Series of Ineleganoloids by Oxidation-State Manipulation of the Carbocyclic Core" Robert A. Craig, Russell C. Smith, Jennifer L. Roizen, Amanda C. Jones, Scott C. Virgil, and Brian M. Stoltz. J. Org. Chem. 2019, 84, 7722–7746.
"Palladium-catalyzed α,β-dehydrogenation of acyclic ester equivalents promoted by a novel electron deficient phosphinooxazoline ligand" Tyler J. Fulton, Brenda Wu, Eric J. Alexy, Haiming Zhang, and Brian M. Stoltz. Tetrahedron 2019, 75, 4104–4109. [Supporting Information].
"Palladium-catalyzed enantioselective decarboxylative allylic alkylation of fully substituted N-acyl indole-derived enol carbonates" Eric J. Alexy, Tyler J. Fulton, Haiming Zhang, and Brian M. Stoltz. Chem. Sci. 2019, 10, 5996–6000. [Supporting Information].
"Characterization of reactive organometallic species via MicroED" Christopher Jones, Matthew Asay, Lee Joon Kim, Jack Kleinsasser, Ambarneil Saha, Tyler J. Fulton, Kevin Berkley, Duilio Cascio, Andrey Malyutin, Matthew Conley, Brian M. Stoltz, Vincent LaVallo, Jose A. Rodriguez, Hosea Nelson. ACS Cent. Sci. 2019, 5. ChemRXiv Preprint.
"Cycloadditions of Oxacyclic Allenes and a Catalytic Asymmetric Entryway to Enantioenriched Cyclic Allenes" Michael M. Yamano, Rachel R. Knapp, Aurapat Ngamnithiporn, Melissa Ramirez, Kendall N. Houk, Brian M. Stoltz, Neil K. Garg. Angew. Chem. Int. Ed. 2019, 58, 5653–5657. [Supporting Information].
"Discussion Addendum for: The Direct Acyl-Alkylation of Arynes. Preparation of Methyl 2-(2-acetylphenyl)acetate" Austin C. Wright and Brian M. Stoltz. Org. Synth. 2019, 96, 80–97.
"An unexpected Ireland–Claisen rearrangement cascade during the synthesis of the tricyclic core of Curcusone C: Mechanistic elucidation by trial-and-error and automatic artificial force-induced reaction (AFIR) computations" Chung Whan Lee, Buck L. H. Taylor, Galina P. Petrova, Ashay Patel, Keiji Morokuma, K. N. Houk, and Brian M. Stoltz. J. Am. Chem. Soc. 2019, 141, 6995–7004.
"Development of a catalytic enantioselective synthesis of the guanacastepene and heptemerone tricyclic core" Andrew M. Harned and Brian M. Stoltz. Tetrahedron 2019, 75, 3166–3177.
"Palladium‐Catalyzed Construction of Quaternary Stereocenters by Enantioselective Arylation of γ‐Lactams with Aryl Chlorides and Bromides" Carina Jette, Irina Geibel, Shoshana Bachman, Masaki Hayashi, Shunya Sakurai, Hideki Shimizu, Jeremy B. Morgan, and Brian Stoltz. Angew. Chem. Int. Ed. 2019, 58, 4297–4301. [Supporting Information].
"Atroposelective Synthesis of PINAP via Dynamic Kinetic Asymmetric Transformation" Seo-Jung Han, Vikram Bhat, Brian M. Stoltz, and Scott C. Virgil. Adv. Synth. Catal. 2019, 361, 441–444. [Supporting Information].
"Intramolecular Hydrogen Shift Chemistry of Hydroperoxy-Substituted Peroxy Radicals" Eric Praske, Rasmus V. Otkjær, John D. Crounse, J. Caleb Hethcox, Brian M. Stoltz, Henrik G. Kjaergaard, and Paul O. Wennberg J. Phys. Chem. A 2018, 123, 590–600. [Supporting Information].
"Concise total syntheses of (–)-jorunnamycin A and (–)-jorumycin enabled by asymmetric catalysis" Eric R. Welin, Aurapat Ngamnithiporn, Max Klatte, Guillaume Lapointe, Gerit M. Pototschnig, Martina S. J. McDermott, Dylan Conklin, Christopher D. Gilmore, Pamela M. Tadross, Christopher K. Haley, Kenji Negoro, Emil Glibstrup, Christian U. Grünanger, Kevin M. Allan, Scott C. Virgil, Dennis J. Slamon, and Brian M. Stoltz. Science 2018, 363, 270–275. [Supporting Information].
"Concise Syntheses of Δ12-Prostaglandin J Natural Products via Stereoretentive Metathesis" Jiaming Li, Tonia S. Ahmed, Chen Xu, Brian M. Stoltz, and Robert H. Grubbs. J. Am. Chem. Soc. 2018, ASAP [Supporting Information].
"Discussion Addendum for: Preparation of (S)-tert-ButylPHOX and (S)-2-Allyl-2-Methylcyclohexanone" Alexander W. Sun and Brian M. Stoltz. Org. Synth. 2018, 95, 439–454.
"The CryoEM Method MicroED as a Powerful Tool for Small Molecule Structure Determination" Christopher G. Jones^†, Michael W. Martynowycz^†, Johan Hattne, Tyler J. Fulton, Brian M. Stoltz, Jose A. Rodriguez, Hosea M. Nelson, and Tamir Gonen. ACS Cent. Sci. 2018, ASAP. ^†Equal Contribution. [Supporting Information]. ChemRXiv Preprint. Caltech Feature Story
"Enantioselective Synthesis of gem-Disubstituted N-Boc Diazaheterocycles via Decarboxylative Asymmetric Allylic Alkylation" Alexander Sun†, Stephan Hess† and Brian M. Stoltz. Chem. Sci. 2018, 10, 788–792. ^†Equal Contribution. [Supporting Information].
"Catalyst-Controlled Selective Functionalization of Unactivated C–H Bonds in the Presence of Electronically Activated C–H Bonds" Wenbin Liu, Zhi Ren, Aaron T. Bosse, Kuangbiao Liao, Elizabeth L. Goldstein, John Bacsa, Djamaladdin G. Musaev, Brian M. Stoltz, and Huw M. L. Davies. J. Am. Chem. Soc. 2018, ASAP. [Supporting Information].
"Palladium-Catalyzed Enantioselective Csp3–Csp3 Cross-Coupling for the Synthesis of (Poly)fluorinated Chiral Building Blocks" Yanhui Lu, Elizabeth L. Goldstein, and Brian M. Stoltz. Org. Lett. 2018, ASAP. [Supporting Information].
"Synergistic O3 + OH oxidation pathway to extremely low-volatility dimers revealed in β-pinene secondary organic aerosol" Christopher M. Kenseth, Yuanlong Huang, Ran Zhao, Nathan F. Dalleska, J. Caleb Hethcox, Brian M. Stoltz, and John H. Seinfeld. Proc. Natl. Acad. Sci. U S A 2018, Just Accepted. [Supporting Information].
"Intermolecular Stereoselective Iridium-Catalyzed Allylic Alkylation: An Evolutionary Account" Samantha E. Shockley, J. Caleb Hethcox, and Brian M. Stoltz. Synlett 2018, Just Accepted.
"General and Practical KOMe/Disilane-Mediated Dehalogenative Deuteration of (Hetero)Arylhalides" Xin Wang, Ming-Hui Zhu, David P Schuman, Dayou Zhong, Wen-Yan Wang, Lin-Yang Wu, Wei Liu, Brian M. Stoltz, and Wen-Bo Liu. J. Am. Chem. Soc. 2018, Just Accepted [Supporting Information].
"Catalytic Enantioselective Synthesis of Acyclic Quaternary Centers: Palladium-Catalyzed Decarboxylative Allylic Alkylation of Fully Substituted Acyclic Enol Carbonates" Eric J. Alexy, Haiming Zhang, and Brian M. Stoltz. J. Am. Chem. Soc. 2018, Just Accepted [Supporting Information].
"Short Enantioselective Formal Synthesis of (–)-Platencin" Christian Defieber, Justin T. Mohr , Gennadii A. Grabovyi, Brian M. Stoltz. Synthesis 2018, Just Accepted [Supporting Information].
"Total Synthesis of the Norhasubanan Alkaloid Stephadiamine" Nina Hartrampf, Nils Winter, Gabriele Pupo, Brian M. Stoltz, and Dirk Trauner. J. Am. Chem. Soc. 2018, Just Accepted [Supporting Information].
"Enantioselective Synthesis of Vicinal All‐Carbon Quaternary Centers via Iridium‐Catalyzed Allylic Alkylation" J. Caleb Hethcox, Samantha E. Shockley, and Brian M. Stoltz. Angew. Chem. Int. Ed. 2018, 57, 1–5. [Supporting Information].
"Enantioselective palladium-catalyzed allylic alkylation reactions in the synthesis of Aspidosperma and structurally related monoterpene indole alkaloids" Beau P. Pritchett and Brian M. Stoltz. Nat. Prod. Rep. 2018, Advance Article.
"Development of a Unified Enantioselective, Convergent Synthetic Approach Toward the Furanobutenolide-Derived Polycyclic Norcembranoid Diterpenes: Asymmetric Formation of the Polycyclic Norditerpenoid Carbocyclic Core by Tandem Annulation Cascade" Robert A. Craig, II, Russell C. Smith, Jennifer L. Roizen, Amanda C. Jones, Scott C. Virgil, and Brian M. Stoltz. J. Org. Chem. 2018, Just Accepted. [Supporting Information].
"Nickel-Catalyzed Enantioselective Allylic Alkylation of Lactones and Lactams with Unactivated Allylic Alcohols" Fa Ngamnithiporn, Carina Jette, Shoshana Bachman, Scott Virgil, and Brian M. Stoltz. Chemical Science 2018, Just Accepted. [Supporting Information].
"The Cyanthiwigin Natural Product Core as a Complex Molecular Scaffold for Comparative Late-Stage C–H Functionalization Studies" Kelly E. Kim, Ashley M. Adams, Nicholas D. Chiappini, J. Du Bois, and Brian M. Stoltz J. Org. Chem. 2018, Just Accepted. [Supporting Information].
"Wolff/Cope Approach to the AB Ring of the Sesterterpenoid Variecolin" Michael R Krout, Christopher Edwin Henry, Thomas Jensen, Kun-Liang (Phil) Wu, Scott C Virgil, and Brian M. Stoltz J. Org. Chem. 2018, Just Accepted. [Supporting Information].
"Atmospheric autoxidation is increasingly important in urban and suburban North America" Eric Praske, Rasmus V. Otkjær, John D. Crounse, J. Caleb Hethcox, Brian M. Stoltz, Henrik G. Kjaergaard, and Paul O. Wennberg. PNAS 2017, Early Edition. [Supporting Information].
"Isocanthine Synthesis via Rh(III)-Catalyzed Intramolecular C–H Functionalization" Anthony Y. Chen, Qianqian Lu, Yao Fu, Richmond Sarpong, Brian M. Stoltz, and Haiming Zhang. JOC 2017, Accepted. [Supporting Information].
"Model Studies To Access the [6,7,5,5]-Core of Ineleganolide Using Tandem Trans lactonization Cope or Cyclopropanation Cope Rearrangements as Key Steps" Jennifer L. Roizen, Amanda C. Jones, Russell C. Smith, Scott C. Virgil, and Brian M. Stoltz. JOC 2017, Accepted. [Supporting Information].
"Catalytic Reduction of Alkyl and Aryl Bromides using Isopropanol" Michael C. Haibach, Brian M. Stoltz, and Robert H. Grubbs. ACIE 2017, Accepted. [Supporting Information].
"Sequential Ruthenium Catalysis for Olefin Isomerization and Oxidation: Application to the Synthesis of Unusual Amino Acids" Marc Liniger, Yiyang Liu, and Brian M. Stoltz. JACS 2017, Just Accepted. [Supporting Information].
"Enantioselective Pd-Catalyzed Decarboxylative Allylic Alkylation of Thiopyranones. Access to Acyclic, Stereogenic α-Quaternary Ketones" Eric J. Alexy, Scott C. Virgil, Michael D. Bartberger, and Brian M. Stoltz. Org. Lett. 2017, ASAP. [Supporting Information].
"Progress towards the total synthesis of hamigerans C and D: a direct approach to an elaborated 6-7-5 carbocyclic core" Doug C. Duquette, Thomas Jensen, and Brian M. Stoltz. J. Antibiot. 2017, Advanced Online Publication. [Supporting Information]. ^†Equal Contribution.
"Enantioselective Catalysis Coupled with Stereodivergent Cyclization Strategies Enables Rapid Syntheses of (+)-Limaspermidine and (+)-Kopsihainanine A" Beau P. Pritchett,† Etienne J. Donckele,† Brian M. Stoltz. ACIE 2017, ASAP. [Supporting Information]. ^†Equal Contribution.
"Enantioselective Synthesis of Acyclic α-Quaternary Carboxylic Acid Derivatives via Iridium-Catalyzed Allylic Alkylation" Samantha Shockley,† John Caleb Hethcox† and Brian Stoltz. ACIE 2017, ASAP. [Supporting Information]. ^†Equal Contribution.
"Enantioselective Total Synthesis of Nigelladine A via Late-Stage C–H Oxidation Enabled by an Engineered P450 Enzyme" Steven A. Loskot, David K. Romney, Frances H. Arnold, and Brian M. Stoltz J. Am. Chem. Soc. 2017, ASAP. [Supporting Information].
"Enantioselective Construction of Acyclic Quaternary Carbon Stereocenters: Palladium-Catalyzed Decarboxylative Allylic Alkylation of Fully Substituted Amide Enolates" Pavel Starkov,† Jared T. Moore,† Douglas C. Duquette, Brian M. Stoltz, and Ilan Marek. J. Am. Chem. Soc. 2017, ASAP. [Supporting Information]. ^†Equal Contribution.
"Asymmetric Synthesis of All-Carbon Quaternary Spirocycles via a Catalytic Enantioselective Allylic Alkylation Strategy" Samantha E. Shockley,† J. Caleb Hethcox,† and Brian M. Stoltz. Tetrahedron Lett. 2017, Accepted. [Supporting Information]. ^†Equal Contribution.
"Polycyclic Furanobutenolide-Derived Cembranoid and Norcembranoid Natural Products: Biosynthetic Connections and Synthetic Efforts" Robert A. Craig II and Brian M. Stoltz. Chem. Rev. 2017, ASAP.
"Ionic and Neutral Mechanisms for C–H Bond Silylation of Aromatic Heterocycles Catalyzed by Potassium tert-Butoxide" Shibdas Banerjee,† Yun-Fang Yang,† Ian D. Jenkins,† Yong Liang, Anton A. Toutov, Wen-Bo Liu, David P. Schuman, Robert H. Grubbs, Brian M. Stoltz, Elizabeth H. Krenske, Kendall N. Houk, and Richard N. Zare. J. Am. Chem. Soc. 2017, ASAP. [Supporting Information]. ^†Equal Contribution.
"Potassium tert-Butoxide-Catalyzed Dehydrogenative C−H Silylation of Heteroaromatics: A Combined Experimental and Computational Mechanistic Study" Wen-Bo Liu,† David P. Schuman,† Yun-Fang Yang,† Anton A. Toutov, Yong Liang, Hendrik F. T. Klare, Nasri Nesnas, Martin Oestreich, Donna G. Blackmond, Scott C. Virgil, Shibdas Banerjee, Richard N. Zare, Robert H. Grubbs, K. N. Houk, and Brian M. Stoltz. J. Am. Chem. Soc. 2017, ASAP. [Supporting Information]. ^†Equal Contribution.
"Enantioselective Iridium-Catalyzed Allylic Alkylation Reactions of Masked Acyl Cyanide Equivalents" J. Caleb Hethcox,^† Samantha E. Shockley,^† and Brian M. Stoltz. Org. Lett. 2017, ASAP. [Supporting Information]. ^†Equal Contribution.
"A Fischer Indolization Strategy toward the Total Synthesis of (–)-Goniomitine" Beau P. Pritchett, Jun Kikuchi, Yoshitaka Numajiri, and Brian M. Stoltz. Heterocycles 2017, Prepress. [Supporting Information].
"Oxidative Fragmentations and Skeletal Rearrangements of Oxindole Derivatives" Hendrik F. T. Klare, Alexander F. G. Goldberg, Douglas C. Duquette, and Brian M. Stoltz* Org. Lett. 2017, ASAP. [Supporting Information].
"Advances in Stereoconvergent Catalysis from 2005 to 2015: Transition-Metal-Mediated Stereoablative Reactions, Dynamic Kinetic Resolutions, and Dynamic Kinetic Asymmetric Transformations" Vikram Bhat, Eric R. Welin, Xuelei Guo, and Brian M. Stoltz. Chem. Rev. 2017, ASAP.
"Alkali metal hydroxide–catalyzed C(sp)–H bond silylation" Anton Toutov,^† Kerry Betz,^† David Phillip Schuman, Wen-bo Liu, Alexey Fedorov, Brian M. Stoltz, and Robert H. Grubbs. J. Am. Chem. Soc. 2017, 139, 1668. [Supporting Information]. ^†Equal Contribution.
"Single-step synthesis of 3-hydroxycarbazoles by annulation of electron-rich anilines and quinones" Eugenia Pushkarskaya, Brian Wong, Chong Han, Simona Capomolla, Chunang Gu, Brian M. Stoltz, Haiming Zhang. Tetrahedron Lett. 2016, 57, 5653. [Supporting Information].
"Iridium-Catalyzed Stereoselective Allylic Alkylation Reactions with Crotyl Chloride" J. Caleb Hethcox,^† Samantha E. Shockley,^† and Brian M. Stoltz. Angew. Chem. Int. Ed. 2016, Early View. [Supporting Information]. ^†Equal Contribution.
"A Second-Generation Synthesis of the Cyanthiwigin Natural Product Core" Kelly E. Kim and Brian M. Stoltz. Org. Lett. 2016, ASAP. [Supporting Information]
"Palladium-Catalyzed Aerobic Intramolecular Aminoacetoxylation of Alkenes Enabled by Catalytic Nitrate" Jiaming Li, Robert H. Grubbs, and Brian M. Stoltz. Org. Lett. 2016, ASAP. [Supporting Information]
"Catalytic Anti-Markovnikov Transformations of Hindered Terminal Alkenes Enabled by Aldehyde-Selective Wacker-Type Oxidation" Kelly E. Kim, Jiaming Li, Robert H. Grubbs, and Brian M. Stoltz. J. Am. Chem. Soc. 2016, ASAP [Supporting Information]
"Enantioselective Pd-Catalyzed Allylic Alkylation Reactions of Dihydropyrido[1,2-a]indolone Substrates: Efficient Syntheses of (−)-Goniomitine, (+)-Aspidospermidine, and (−)-Quebrachamine" Beau P. Pritchett, Jun Kikuchi, Yoshitaka Numajiri, and Brian M. Stoltz. Angew. Chem. Int. Ed. 2016, Early View. [Supporting Information]
"Enantioconvergent catalysis" Justin T. Mohr, Jared T. Moore, and Brian M. Stoltz. Beilstein J. Org. Chem. 2016, 12, 2038.
"Potassium tert-Butoxide–Catalyzed Dehydrogenative Cross-Coupling of Heteroarenes with Hydrosilanes" Anton A. Toutov, Wen-Bo Liu, Brian M. Stoltz and Robert H. Grubbs. Org. Synth., 2016, 93, 263.
"Iridium-Catalyzed Diastereo-, Enantio-, and Regioselective Allylic Alkylation with Prochiral Enolates" J. Caleb Hethcox, Samantha E. Shockley,^† and Brian M. Stoltz. ACS Catal., 2016, 6, 6207. ^†Equal Contribution.
"Enantioselective, Convergent Synthesis of the Ineleganolide Core by a Tandem Annulation Cascade" Rob Craig, Jennifer L. Roizen, Russell Smith, Amanda C. Jones, Scott Virgil and Brian M. Stoltz. Chem. Sci, 2016, Advance Article. [Supporting Information]
"Escherichia coli K1 modulates peroxisome proliferator-activated receptor-gamma and glucose transporter-1 at the blood-brain barrier in neonatal meningitis" Subramanian Krishnan, Alexander C. Chang, Brian M. Stoltz, and Nemani V. Prasadarao. J. Infect. Dis., 2016, Just Accepted. This article was featured in a press release from Children's Hospital, Los Angeles
"Preparation of 1,5-Dioxaspiro[5.5]undecan-3-one" Robert A. Craig, II, Russell C. Smith, Beau P. Pritchett, Benzi I. Estipona, and Brian M. Stoltz. Org. Synth., 2016, 93, 210.
"Ni-Catalyzed Enantioselective C-Acylation of α-Substituted Lactams" Masaki Hayashi, Shoshana Bachman, Satoshi Hashimoto, Chad C. Eichman, and Brian M. Stoltz. J. Am. Chem. Soc. 2016, Just Accepted. [Supporting Information]
"Synthesis of Aryl Ketoamides via Aryne Insertion into Imides" " Austin C. Wright, Christopher K. Haley, Guillaume Lapointe, and Brian M. Stoltz. Org. Lett. 2016, ASAP. [Supporting Information]
"Nickel-Catalyzed Intramolecular C−O Bond Formation: Synthesis of Cyclic Enol Ethers" " Seo-Jung Han, Ryohei Doi, Brian M. Stoltz. Angew. Chem. Int. Ed. 2016, Early View. [Supporting Information]
"A mild and efficient approach to enantioenriched α-hydroxyethyl α,β-unsaturated δ-lactams" " Seo-Jung Han, Brian M. Stoltz. Tetrahedron Lett. 2016, In Press. [Supporting Information]
"Enantioselective Synthesis of Caprolactam and Enone Precursors to the Heterocyclic DEFG Ring System of Zoanthenol" " Jeffrey T. Bagdanoff, Douglas C. Behenna, Jennifer L. Stockdill, and Brian M. Stoltz. Eur. J. Org. Chem. 2016, Early View. [Supporting Information]
"Enantioselective γ-Alkylation of α,β-Unsaturated Malonates and Ketoesters by a Sequential Ir-Catalyzed Asymmetric Allylic Alkylation/Cope Rearrangement" Wen-Bo Liu,^† Noriko Okamoto,^† Eric J. Alexy, Allen Y. Hong, Kristy Tran, and Brian M. Stoltz. J. Am. Chem. Soc. 2016, 138, 5234. ^†Equal Contribution. [Supporting Information]. Check out the Synfacts highlight!
"Catalytic enantioselective total synthesis of (+)-eucomic acid" " Benzi I. Estipona,^† Beau P. Pritchett, Robert A. Craig II, Brian M. Stoltz. Tetrahedron, 2016, In Press. ^†Caltech Undergrad. [Supporting Information]
Synthetic Applications and Methodological Developments of Donor-Acceptor Cyclopropanes and Related Compounds " Nicholas R. O’Connor, John L. Wood, Brian M. Stoltz. Isr. J. Chem., 2016, Early View.
"Development of a simple system for the oxidation of electron-rich diazo compounds to ketones" Nicholas R. O’Connor, Peter Bolgar, Brian M. Stoltz. Tetrahedron Lett., 2016, 57, 849. [Supporting Information]
"Total Synthesis and Characterization of 7-Hypoquinuclidonium Tetrafluoroborate and 7-Hypoquinuclidone BF3 Complex" Marc Liniger, David G. VanderVelde, Michael K. Takase, Mona Shahgholi, Brian M. Stoltz. JACS, 2016, ASAP. [Supporting Information]
"Catalytic C–H bond silylation of aromatic heterocycles" Anton A Toutov,^† Wen-Bo Liu,^† Kerry N. Betz, Brian M. Stoltz. Robert H. Grubbs. Nat. Protoc., 2015, 10, 1897. ^†Equal Contribution.
"Palladium-Catalyzed Enantioselective Decarboxylative Allylic Alkylation of Cyclopentanones" Robert A. Craig II,^† Steven A. Loskot,^† Justin T. Mohr, Douglas C. Behenna, Andrew M. Harned, Brian M. Stoltz. Org. Lett., 2015, ASAP. ^†Equal Contribution. [Supporting Information]
"Label-free detection of single nanoparticles and biological molecules using microtoroid optical resonators" Judith Su, Alexander F.G. Goldberg, Brian M. Stoltz. Light Sci. Appl., 2015, Accepted Article Preview
"Preparation of (S)-tert-ButylPyOx and Palladium-Catalyzed Asymmetric Conjugate Addition of Arylboronic Acids" Jeffrey C. Holder, Samantha E. Shockley, Mario P. Wiesenfeldt, Hideki Shimizu, Brian M. Stoltz. Org Synth., 2015, 92, 247.
"Palladium(II)-Catalyzed Allylic C-H Oxidation of Hindered Substrates Featuring Tunable Selectivity Over Extent of Oxidation" Xiangyou Xing, Nicholas R. O’Connor,, Brian M. Stoltz. Angew. Chem. Int. Ed., 2015, Early View. [Supporting Information]
"Palladium-Catalyzed Decarbonylative Dehydration for the Synthesis of α-Vinyl Carbonyl Compounds and Total Synthesis of (−)-Aspewentins A, B, and C" Yiyang Liu, Scott C. Virgil, Robert H. Grubbs, Brian M. Stoltz. Angew. Chem. Int. Ed., 2015, Early View. [Supporting Information]
"Palladium-Catalyzed Asymmetric Conjugate Addition of Arylboronic Acids to α,β-Unsaturated Cyclic Electrophiles" Samantha E. Shockley, Jeffrey C. Holder, Brian M. Stoltz. Org. Process Res. Dev., 2015, Article ASAP.
"An Efficient Protocol for the Palladium-Catalyzed Asymmetric Decarboxylative Allylic Alkylation Using Low Palladium Concentrations and a Palladium(II) Precatalyst" Alexander N. Marziale, Douglas C. Duquette, Robert A. Craig II, Kelly E. Kim, Marc Liniger, Yoshitaka Numajiri, Brian M. Stoltz. Adv.Synth. Catal. 2015, 357, 2238. [Supporting Information]
"Synthesis and Exploration of Electronically Modified (R)-5,5-Dimethyl-(p-CF3)3-i-PrPHOX in Palladium-Catalyzed Enantio- and Diastereoselective Allylic Alkylation: A Practical Alternative to (R)-(p-CF3)3-t-BuPHOX" Robert A. Craig II, Brian M. Stoltz. Tet. Lett. 2015, 56, 4670. [Supporting Information]
"Construction of Tertiary Chiral Centers by Pd-catalyzed Asymmetric Allylic Alkylation of Prochiral Enolate Equivalents" Yusuke Kita, Yoshitaka Numajiri, Noriko Okamoto, Brian M. Stoltz. Tetrahedron 2015, 71, 6349. [Supporting Information]
"Exceedingly Efficient Synthesis of (±)-Grandifloracin and Acylated Analogues" Magnus Bergner, Douglas C. Duquette, Linda Chio, Brian M. Stoltz. Org. Lett. 2015, 17, 3008. [Supporting Information]
"Enantioselective Synthesis of Dialkylated N-Heterocycles by Palladium-Catalyzed Allylic Alkylation" Yoshitaka Numajiri, Gonzalo Jiménez-Osés, Bo Wang, Ken N. Houk , Brian M. Stoltz Org. Lett. 2015, 17, 1082. [Supporting Information]
"Catalytic Enantioselective Construction of Quaternary Stereocenters: Assembly of Key Building Blocks for the Synthesis of Biologically Active Molecules" Yiyang Liu, Seo-Jung Han, Wen-Bo Liu, and Brian M. Stoltz Acc. Chem. Res. 2015, 48, 740.
"Silylation of C–H bonds in Aromatic Heterocycles by an Earth-abundant Metal Catalyst" Anton A. Toutov, Wen-Bo Liu, Kerry N. Betz, Alexey Fedorov, Brian M. Stoltz, Robert H. Grubbs Nature 2015, 518, 80. [Supporting Information]
"Selective Syntheses of Leuconolam, Leuconoxine, and Mersicarpine Alkaloids from a Common Intermediate through Regiocontrolled Cyclizations by Staudinger Reactions" Zining Li, Qian Geng, Zhe Lv, Beau P. Pritchett, Katsuaki Baba, Yoshitaka Numajiri, Brian M. Stoltz, Guangxin Liang Org. Chem. Front. 2015, 2, 236. [Supporting Information]
"Enantioselective Synthesis of α-Quaternary Mannich Adducts by Palladium-Catalyzed Allylic Alkylation: Total Synthesis of (+)-Sibirinine" Yoshitaka Numajiri, Beau P. Pritchett, Koji Chiyoda, Brian M. Stoltz J. Am. Chem. Soc. 2015, 137, 1040. [Supporting Information]
"Mechanistic Analysis of an Asymmetric Palladium-Catalyzed Conjugate Addition of Arylboronic Acids to β-Substituted Cyclic Enones" Cornelia L. Boeser, Jeffrey C. Holder, Buck L. H. Taylor, K. N. Houk, Brian M. Stoltz, Richard N. Zare. Chem. Sci. 2015, 6, 1917. [Supporting Information]
"Synthesis of Diverse β-Quaternary Ketones via Palladium-Catalyzed Asymmetric Conjugate Addition of Arylboronic Acids to Cyclic Enones" Jeffrey C. Holder, Emmett D. Goodman, Kotaro Kikushima, Michele Gatti, Alexander N. Marziale, Brian M. Stoltz. Tetrahedron 2014, 71, 5781.
"Evolution of a Unified, Stereodivergent Approach to the Synthesis of Communesin F and Perophoramidine" Seo-Jung Han, Florian Vogt, Jeremy A. May, Shyam Krishnan, Michele Gatti, Scott C. Virgil, Brian M. Stoltz. J. Org Chem. 2014, 80, 528. [Supporting Information]
"A Catalytic, Enantioselective Formal Synthesis of (+)-Dichroanone and (+)-Taiwaniaquinone H" Samantha E. Shockley, Jeffrey C. Holder, Brian M. Stoltz. Org. Lett. 2014, 16, 6362. [Supporting Information]
"Enantioselective Synthesis of α-Secondary and α-Tertiary Piperazin-2-ones and Piperazines by Catalytic Asymmetric Allylic Alkylation" Katerina M. Korch, Christian Eidamshaus, Douglas C. Behenna, Sangkil Nam, David Horne, Brian M. Stoltz. Angew. Chem. Int. Ed. 2014, 54, 179. Also in press here. [Supporting Information]
"Stereochemical evaluation of bis(phosphine) copper catalysts for the asymmetric alkylation of 3-bromooxindoles with α-arylated malonate esters" Chung Whan Lee, Seo-Jung Han, Scott C. Virgil, Brian M. Stoltz Tetrahedron 2014, 71, 3666. [Supporting Information]
"Formal total syntheses of classic natural product target molecules via palladium-catalyzed enantioselective alkylation" Yiyang Liu, Marc Liniger, Ryan M. McFadden, Jenny L. Roizen, Jacquie Malette, Corey M. Reeves, Douglas C. Behenna, Masaki Seto, Jimin Kim, Justin T. Mohr, Scott C. Virgil and Brian M. Stoltz. Beilstein J. Org. Chem. 2014, 10, 2501. [Supporting Information]
"The Total Syntheses of Basiliolide C, epi-Basiliolide C, and Protecting-Group-Free Total Syntheses of Transtaganolides C and D" Jonny R. Gordon, Hosea M. Nelson, Scott C. Virgil, Brian M. Stoltz. J. Org. Chem. 2014, 79. 9740. [Supporting Information]
"A New Method for the Cleavage of Nitrobenzyl Amides and Ethers" Seo-Jung Han, Gabriel Fernando de Melo, Brian M. Stoltz. Tet. Lett. 2014, 55, 6467.
"Highly functionalized donor–acceptor cyclopropanes applied toward the synthesis of the Melodinus alkaloids" Alexander F.G. Goldberg, Robert A. Craig II,^† Nicholas R. O’Connor,^† Brian M. Stoltz. Tet. Lett. 2014, 56, 2983. ^†Equal Contribution
"A Diastereodivergent Synthetic Strategy for the Syntheses of Communesin F and Perophoramidine" Seo-Jung Han, Florian Vogt, Shyam Krishnan, Jeremy A. May, Michele Gatti, Scott C. Virgil, Brian M. Stoltz. Org. Lett. 2014, 16, 3316. [Supporting Information]
"Biosynthesis and Chemical Synthesis of Presilphiperfolanol Natural Products" Allen Y. Hong, Prof. Brian M. Stoltz. Angew. Chem. Int. Ed. 2014, 53, 5248. Also in press here.
"Development of (Trimethylsilyl)ethyl Ester Protected Enolates and Applications in Palladium-Catalyzed Enantioselective Allylic Alkylation: Intermolecular Cross-Coupling of Functionalized Electrophiles" Corey M. Reeves, Douglas C. Behenna, Prof. Brian M. Stoltz. Org. Lett. 2014, 16, 2314. [Supporting Information]
"Palladium-catalyzed decarboxylative allylic alkylation of diastereomeric β-ketoesters" Sandy Ma, Corey M. Reeves, Robert A. Craig II, Prof. Brian M. Stoltz. Tetrahedron 2014, 70, 4208. [Supporting Information]
"Stereoselective Lewis Acid Mediated (3+2) Cycloadditions of N-H- and N-Sulfonylaziridines with Heterocumulenes" Robert A. Craig II, Nicholas R. O'Connor, Dr. Alexander F. G. Goldberg, Prof. Brian M. Stoltz. Chem. — Eur. J. 2014, 20. 4806. [Supporting Information]
"Toward a Symphony of Reactivity: Cascades Involving Catalysis and Sigmatropic Rearrangements" Amanda Jones, Brian M. Stoltz*, Jeremy A. May, Richmond Sarpong. Angew. Chem. Int. Ed. 2014, 53, 2556. Also in press at Angew. Chem. 2014 126, 2590.
"Gas Phase Production and Loss of Isoprene Epoxydiols" Kelvin H. Bates, John D. Crounse, Jason M. St. Clair, Nathan B. Bennett, Tran B. Nguyen, John H. Seinfeld, Brian M. Stoltz, and Paul O. Wennberg. J. Phys. Chem. A 2014, 118, 1237-1246. [Supporting Information]
"Palladium-Catalyzed Decarbonylative Dehydration of Fatty Acids for the Production of Linear Alpha Olefins" Yiyang Liu, Kelly E. Kim, Myles B. Herbert, Alexey Fedorov, Robert H. Grubbs, Brian M. Stoltz. Adv. Synth. Catal. 2014, 356, 130. [Supporting Information]. Additionally, this article was featured on the organic-chemistry.org webportal, which can be accessed here.
"A Unified Approach to the Daucane and Sphenolobane Bicyclo[5.3.0]decane Core: Enantioselective Total Syntheses of Daucene, Daucenal, Epoxydaucenal B, and 14-para-Anisoyloxydauc-4,8-diene" Nathan B. Bennett, and Brian M. Stoltz. Chem. — Eur. J. 2013, 52, 17745. [Supporting Information]
"Enantio-, Diastereo- and Regioselective Iridium-Catalyzed Asymmetric Allylic Alkylation of Acyclic β-Ketoesters" Wen-Bo Liu, Corey M. Reeves, and Brian M. Stoltz. J. Am. Chem. Soc. 2013, 135, 17298. [Supporting Information]This article was Synfact of the Month!
"Asymmetric Synthesis of QUINAP via Dynamic Kinetic Resolution" Vikram Bhat, Su Wang, Brian M. Stoltz, and Scott C Virgil. J. Am. Chem. Soc. 2013, 135, 16829. [Supporting Information] This article was featured in Synfacts!
"Angiotensin receptor I - A novel target for preventing neonatal meningitis in mice by Escherichia coli K1" Subramanian Krishnan, Muthusamy V. Shanmuganathan, Douglas Behenna, Brian M. Stoltz and Nemani V. Prasadarao. J. Infect. Dis. 2013, Accepted Manuscript. [Supporting Information]
"Mechanism and Enantioselectivity in Palladium-Catalyzed Conjugate Addition of Arylboronic Acids to β-Substituted Cyclic Enones: Insights from Computation and Experiment" Jeffrey C. Holder, Lufeng Zou, Alexander N. Marziale, Peng Liu, Yu Lan, Michele Gatti, Kotaro Kikushima, K. N. Houk, and Brian M. Stoltz. J. Am. Chem. Soc. 2013, 135, 14996. [Supporting Information]
"A scalable synthesis of the (S)-4-(tert-butyl)-2-(pyridin-2-yl)-4,5-dihydrooxazole ((S)-t-BuPyOx) ligand" Hideki Shimizu, Jeffrey C. Holder and Brian M. Stoltz. Beilstein J. Org. Chem. 2013, 9, 1637. [Supporting Information]
"Construction of Vicinal Tertiary and All-Carbon Quaternary Stereocenters via Ir-Catalyzed Regio‑, Diastereo‑, and Enantioselective Allylic Alkylation and Applications in Sequential Pd Catalysis" Wen-Bo Liu, Corey M. Reeves, Scott C. Virgil, and Brian M. Stoltz. J. Am. Chem. Soc. 2013, ASAP. [Supporting Information] This article was featured in Synfacts!
"Enantioselective Synthesis of the 5–6–7 Carbocyclic Core of the Gagunin Diterpenoids" Grant M. Shibuya , John A. Enquist , Jr., and Brian M. Stoltz. Org. Lett. 2013, ASAP. [Supporting Information]
"Selective Nucleic Acid Capture with Shielded Covalent Probes" CJeffrey R. Vieregg, Hosea M. Nelson, Brian M. Stoltz, and Niles A. Pierce. J. Am. Chem. Soc. 2013, ASAP. [Supporting Information]
"Enantioselective Construction of α-Quaternary Cyclobutanones by Catalytic Asymmetric Allylic Alkylation" Corey M. Reeves, Christian Eidamshaus, Jimin Kim, and Brian M. Stoltz. Angew. Chem. Int. Ed. 2013, 52, 6718. [Supporting Information]
"Total Syntheses of (−)-Transtaganolide A, (+)-Transtaganolide B, (+)-Transtaganolide C, and (−)-Transtaganolide D and Biosynthetic Implications" Hosea M. Nelson, Jonny R. Gordon, Scott C. Virgil, and Brian M. Stoltz. Angew. Chem. Int. Ed. 2013, 52, 6699. [Supporting Information]
"The Construction of All-Carbon Quaternary Stereocenters by Use of Pd-Catalyzed Asymmetric Allylic Alkylation Reactions in Total Synthesis" Allen Y. Hong and Brian M. Stoltz. Eur. J. Org. Chem. 2013, 14, 2745.
"Development of a palladium-catalyzed decarboxylative cross-coupling of (2-azaaryl)carboxylates with aryl halides" Christopher K. Haley, Christopher D. Gilmore, Brian M. Stoltz. Tetrahedron. 2013, 69, 5732.
"Expanding Insight into Asymmetric Palladium-Catalyzed Allylic Alkylation of N-Heterocyclic Molecules and Cyclic Ketones" Nathan B. Bennett,^† Douglas C. Duquette,^† Jimin Kim, Wen-Bo Liu, Alexander N. Marziale, Douglas C. Behenna, Scott C. Virgil, and Brian M. Stoltz. Chem. — Eur. J. 2013, 19, 4414. [Supporting Information]. ^†Equal Contribution
"Use of a palladium(II)-catalyzed oxidative kinetic resolution in synthetic efforts toward bielschowskysin" Michael E. Meyer, John H. Phillips, Eric M. Ferreira, and Brian M. Stoltz. Tetrahedron 2013, In Press.
"Palladium-Catalyzed Asymmetric Conjugate Addition of Arylboronic Acids to Heterocyclic Acceptors" Jeffrey C. Holder,^† Alexander N. Marziale,^† Michele Gatti, Bin Mao, and Brian M. Stoltz. Chem. — Eur. J. 2012, 19, 74. [Supporting Information]. ^†Equal Contribution
"Rapid and Convergent Synthesis of a 2,4’-Linked Tri-oxazole in an Approach to Poly-oxazoles" Daniel D. Caspi, Haiming Zhang, Scott C. Virgil, Fabian M. Piller, and Brian M. Stoltz. Heterocycles. 2012, 86, 1003. [Supporting Information].
"The Reaction Mechanism of the Enantioselective Tsuji Allylation: Inner-Sphere and Outer-Sphere Pathways, Internal Rearrangements, and Asymmetric C–C Bond Formation" John A. Keith, Douglas, C. Behenna, Nathaniel Sherden, Justin T. Mohr, Sandy Ma, Smaranda C. Marinescu, Robert J. Nielsen, Jonas Oxgaard, Brian M. Stoltz and William A. Goddard, III. J. Am. Chem. Soc. 2012, 134, 19050. [Supporting Information].
"Enantioselective Synthesis of a Hydroxymethyl-cis-1,3-cyclopentenediol Building Block" Robert A. Craig, II, Jennifer L. Roizen, Russell C. Smith, Amanda C. Jones, and Brian M. Stoltz. Org. Lett. 2012, 14, 5716. [Supporting Information].
"Lewis Acid Mediated (3 + 2) Cycloadditions of Donor–Acceptor Cyclopropanes with Heterocumulenes" Alexander F. G. Goldberg, Nicholas R. O'Connor,^† Robert A. Craig, II^† and Brian M. Stoltz. Org. Lett. 2012, 14, 5314. [Supporting Information]. ^†Equal Contribution
"Enantioselective Total Synthesis of the Reported Structures of (–)-9-epi-Presilphiperfolan-1-ol and (–)-Presilphiperfolan-1-ol: Structural Confirmation and Reassignment and Biosynthetic Insights." Allen Y. Hong and Brian M. Stoltz. Angew. Chem. Int. Ed. 2012, 51, 9674. [Supporting Information]. This article was featured in Synfacts!
"A C–N Insertion of β-Lactam to Benzyne: Unusual Formation of Acridone" Jimin Kim and Brian M. Stoltz. Tetrahedron Lett. 2012, 53, 4994.
"A Comprehensive History of Arynes in Natural Product Total Synthesis" Pamela M. Tadross and Brian M. Stoltz. Chem. Rev. 2012, 112, 3550.
"Enantioselective construction of quaternary N-heterocycles by palladium-catalysed decarboxylative allylic alkylation of lactams" Douglas C. Behenna, Yiyang Liu, Taiga Yurino, Jimin Kim, David E. White, Scott C. Virgil and Brian M. Stoltz. Nature Chem. 2012, 4, 130. [Supporting Information]. This article was featured in a press release entitled "Caltech Chemists Devise Chemical Reaction that Holds Promise for New Drug Development".
"Palladium-catalyzed asymmetric alkylation in the synthesis of cyclopentanoid and cycloheptanoid core structures bearing all-carbon quaternary stereocenters" Allen Y. Hong, Nathan B. Bennett, Michael R. Krout, Thomas Jensen, Andrew M. Harned, Brian M. Stoltz. Tetrahedron 2011, 67, 10234. [Supporting Information].
"Enantioselective Decarboxylative Alkylation Reactions: Catalyst Development, Substrate Scope, and Mechanistic Studies" Douglas C. Behenna, Justin T. Mohr, Nathaniel H. Sherden, Smaranda C. Marinescu, Andrew M. Harned, Kousuke Tani, Masaki Seto, Sandy Ma, Zoltán Novák, Michael R. Krout, Ryan M. McFadden, Jennifer L. Roizen, John A. Enquist Jr., David E. White, Samantha R. Levine, Krastina V. Petrova, Akihiko Iwashita, Scott C. Virgil, Brian M. Stoltz. Chem. — Eur. J. 2011, 17, 14199. [Supporting Information].
"Synthesis of enantioenriched γ-quaternary cycloheptenones using a combined allylic alkylation/Stork–Danheiser approach: preparation of mono-, bi-, and tricyclic systems" Nathan B. Bennett, Allen Y. Hong, Andrew M. Harned and Brian M. Stoltz. Org. Biomol. Chem. 2012, 10, 56. [Supporting Information]. (This article was one of the top ten downloaded articles for the month of October!)
"A Palladium-Catalyzed Vinylcyclopropane (3 + 2) Cycloaddition Approach to the Melodinus Alkaloids" Alexander F. G. Goldberg and Brian M. Stoltz. Org. Lett. 2011, 13, 4474. [Supporting Information] (This article was among the top 20 accessed articles for the month of July).
"Total Syntheses of Cyanthiwigins B, F, and G" John A. Enquist Jr., Scott C. Virgil and Brian M. Stoltz. Chem. – Eur. J. 2011, 17, 9957. [Supporting Information].
"A rapid and convergent synthesis of the integrastatin core" Pamela M. Tadross, Pradeep Bugga and Brian M. Stoltz. Org. Biomol. Chem. 2011, 9, 5354. [Supporting Information]. (This article was selected as an OBC HOT article, and was among the top 10 accessed articles of the month).
"The Catalytic Enantioselective Total Synthesis of (+)-Liphagal" Joshua J. Day, Ryan M. McFadden, Scott C. Virgil, Helene Kolding, Jennifer L. Alleva, and Brian M. Stoltz. Angew. Chem., Int. Ed. 2011, 50, 6814. [Supporting Information]. This article was featured as the SYNFACT of the Month!
"Palladium-Catalyzed, asymmetric Baeyer–Villiger oxidation of prochiral cyclobutanones with PHOX ligands" Kimberly S. Petersen and Brian M. Stoltz. Tetrahedron 2011, 67, 4352-4357. (This article was highlighted in Org. Process Res. Dev. as an item of interest!)
"Palladium-Catalyzed Asymmetric Conjugate Addition of Arylboronic Acids to Five-, Six-, and Seven-Membered β-Substituted Cyclic Enones: Enantioselective Construction of All-Carbon Quaternary Stereocenters" Kotaro Kikushima, Jeffrey C. Holder, Michele Gatti, and Brian M. Stoltz. J. Am. Chem. Soc. 2011, 1336902. [Supporting Information]. This article was featured as the SYNFACT of the Month!
"Benzannulated Bicycles by Three-Component Aryne Reactions" Kevin M. Allan, Christopher D. Gilmore, and Brian M. Stoltz. Angew. Chem., Int. Ed. 2011, 50, 4488. [Supporting Information]. This article was featured in an Angew. Chem. Highlight article!
"A General Approach to the Basiliolide/Transtaganolide Natural Products: Total Syntheses of Basiliolide B, epi-8-Basiliolide B, Transtaganolide C, and Transtaganolide D" Hosea M. Nelson, Kei Murakami, Scott C. Virgil, and Brian M. Stoltz. Angew. Chem., Int. Ed. 2011, 50, 3688. [Supporting Information]. This article was featured in Synfacts!
"Reversible inhibitor of p97, DBeQ, impairs both ubiquitin-dependent and autophagic protein clearance pathways" Tsui-Fen Chou, Steve J. Brown, Dmitriy Minond, Brian E. Nordin, Kelin Li, Amanda C. Jones, Peter Chase, Patrick R. Porubsky, Brian M. Stoltz, Frank J. Schoenen, Matthew P. Patricelli, Peter Hodder, Hugh Rosen, and Raymond J. Deshaies. P. Natl. Acad. Sci. USA 2011, 108, 4834. [Supporting Information]
"Ring-Contraction Strategy for the Practical, Scalable, Catalytic Asymmetric Synthesis of Versatile γ-Quaternary Acylcyclopentenes" Allen Y. Hong, Michael R. Krout, Thomas Jensen, Nathan B. Bennett, Andrew M. Harned, and Brian M. Stoltz. Angew. Chem., Int. Ed. 2011, 50, 2756. [Supporting Information]
"A Catalytic, Asymmetric Formal Synthesis of (+)-Hamigeran B" Herschel Mukherjee, Nolan T. McDougal, Scott C. Virgil, and Brian M. Stoltz. Org Lett. 2011, 13, 825. [Supporting Information]

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